Chromium – Key for stainless steel production and various industrial uses

£5.35

When you think of chromium, you probably think of chromium plating, a.k.a. chrome. It has another more prevalent use, however. Chromium is a key ingredient in stainless steel. Basically, it is what makes the steel stainless. As such, chromium is an important element in the steel industry and it has been for hundreds of years.

In 1797, the first pure chromium metal was created by French Chemist Nicholas-Louis Vauguelin. Before then, it had been used in dyes and paints, but this marked chromium’s first use in metallurgy. Then, in 1912, Harry Brearley was trying to find a more resilient metal for gun barrels in the U.K. when he created stainless steel. Elsewhere, Elwood Haynes in the US and engineers at Krupp in Germany were also working on chromium-steel alloys. With the invention of the electric arc furnace, which is used in chromite smelting, large scale production became possible.

Chromium, periodic symbol Cr, has a high melting point (2,150°C), is corrosion resistant, and is aesthetically pleasing. By itself it is brittle however, so combining it with steel greatly increased its strength. Conversely, the addition of chromium to steel greatly increased its corrosion resistance.

To make chromium, first chromite ore is mined. Via a smelting process, this is converted to ferrochromium alloys. These alloys consist mainly of chromium and iron with small amounts of carbon and silicone. In 2009, 5.9 million tons of ferrochromium were produced worldwide. Over 90% went to the production of stainless steel. In order to be considered “stainless,” the steel alloy must contain at least 11-12% Chromium. Some stainless steel contains up to 30% Chromium.

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Description

What is stainless steel ?
Stainless steel is the generic name for a number of different steels used primarily for
their resistance to corrosion. The one key element they all share is a certain
minimum percentage (by mass) of chromium: 10.5%. Although other elements,
particularly nickel and molybdenum, are added to improve corrosion resistance,
chromium is always the deciding factor. The vast majority of steel produced in the
world is carbon and alloy steel, with the more expensive stainless steels representing
a small, but valuable niche market.
What causes corrosion?
Only metals such as gold and platinum are found naturally in a pure form – normal
metals only exist in nature combined with other elements. Corrosion is therefore a
natural phenomena, as nature seeks to combine together elements which man has
produced in a pure form for his own use. Iron occurs naturally as iron ore. Pure iron
is therefore unstable and wants to “rust”; that is, to combine with oxygen in the
presence of water. Trains blown up in the Arabian desert in the First World War are
still almost intact because of the dry rainless conditions. Iron ships sunk at very great
depths rust at a very slow rate because of the low oxygen content of the sea water .
The same ships wrecked on the beach, covered at high tide and exposed at low tide,
would rust very rapidly. For most of the Iron Age, which began about 1000 BC, cast
and wrought iron was used; iron with a high carbon content and various unrefined
impurities. Steel did not begin to be produced in large quantities until the nineteenth
century. Carbon steel can be defined as an alloy of a small content of carbon
combined with well refined iron. Despite its various additions stainless steel still
behaves as steel, it is not like the nickel alloys that are really alloys of a number of
different metals, iron only being one. Even highly alloyed stainless steel grades such
as 316 are a minimum of 62% iron.
Carbon steels without any protection will form a coating of rust which will in a sense
protect the rest of the steel. So constantly removing the rust exposes a new fresh
layer of steel to be attacked. This is called general corrosion. Various coatings will
impede the rusting process, in particular painting, coating with zinc (galvanised steel),

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